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Need help with the MCAT question!

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Hey, SDNers! I needed some help with one of the MCAT questions. And thanks in advance for all the help :)

Please see the attached image file.

The question is... which of the two molecules would be better at absorbing water? I went with the first one (wrong answer choice) and my reasoning is that the second molecule may form INTRAmolecular hydrogen bonding which will prevent/lower INTERmolecular hydrogen bonding with the solvent (water) and therefore reduce its water absorbing capabilities....

Need help with the MCAT question!

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